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Advert for S.D. Humphrey, Photographic Chemist 
1858 
  
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Google Books 
 
LL/34672 
  
Published in "Treatise of photography on collodion" by Charles Walkdeck and Peter Neff, Jr, (Second edition, Cincinnati, Longley Brothers, 1858).
 
Note the mention of Ambrotypes and Melainotypes. 
 

 
  
 
  
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